| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 42932 | Applied Catalysis A: General | 2009 | 7 Pages |
The influence of various synthesis variables on the physico-chemical properties of mesoporous stannosilicate molecular sieves with MCM-48 structure (Sn-MCM-48) has been investigated. Sn-MCM-48 has been used as a new heterogeneous catalyst in solvent-free Mukaiyama-type aldol reactions. Invariably, the β-hydroxy ester selectivity was found to be 100% irrespective of the conversion level. The product yield was found to increase, to reach a maximum (70%), and then to decrease with the increase in tin content.
Graphical abstractSynthesis variables such as synthesis time, molar SiO2/SnO2 ratios in the starting gel composition, silica source and tin sources affect the physico-chemical properties of mesoporous stannosilicate molecular sieves with MCM-48 structure (Sn-MCM-48). For the first time, Sn-MCM-48 has been used as a new heterogeneous catalyst in solvent-free Mukaiyama-type aldol reaction.Figure optionsDownload full-size imageDownload as PowerPoint slide
