Effect of adding CaO to ZrO2 support on nickel catalyst activity in dry reforming of methane

Nickel catalysts with a load of 5 wt% Ni, supported on pure ZrO2 and ZrO2 stabilized with 4, 8 and 14 mol% CaO, were prepared by the polymerization method. The samples were characterized by X-ray diffraction (XRD), temperature-programmed reduction with hydrogen (TPR-H2), specific surface area (BET) and impedance spectroscopy (IS) and tested in the carbon dioxide reforming of methane. The XRD patterns showed the presence of the oxide precursor (NiO) and the tetragonal phase of CaO–ZrO2 solid solutions. According to the TPR-H2 analysis, the reduction of various NiO species was influenced by the support composition. The electrical properties of the support have a proportional effect on the catalytic activities. Catalytic tests were done at 800 °C for 6 h and the composition of the gaseous products and the catalytic conversion depended on the CaO–ZrO2 solid solution composition and its influence on supported NiO species. A direct relation was found between the variation in the electrical conductivity of the support, the nickel species supported on it and the performance in the catalytic tests.

Graphical abstractNickel catalysts supported on CaO–ZrO2 solid solutions were tested in dry reforming of methane where the catalytic activity was influenced by the support composition showing the best performance with 8 mol% of CaO, decreasing to higher values of CaO. The mobility of the oxygen vacancies on the supports has a proportional effect on the catalytic performance.Figure optionsDownload full-size imageDownload as PowerPoint slide