| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 43263 | Applied Catalysis A: General | 2008 | 8 Pages |
Abstract
A cyclo-dodecene yield â¥90% can be attained in liquid phase hydrogenation of 1,5,9-cis,trans,trans-cyclo-dodecatriene on Pd catalysts of eggshell type if the hydrogen concentration is kept at a low level. Ab initio Hartree-Fock calculations of the molecular structures of cyclododecadienes have pointed at the crucial role of both cyclododecadienes and hydrogen adsorption on nanostructured surfaces of palladium.
Related Topics
Physical Sciences and Engineering
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Catalysis
Authors
J. Gaube, W. David, R. Sanchayan, S. Roy, F. Müller-Plathe,