| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 44062 | Applied Catalysis A: General | 2007 | 5 Pages |
Carbon-supported palladium catalysts were prepared by ion-exchange and precipitation/deposition methods on various activated carbons. Pd/carbon catalysts with Pd particles ranging from 1.5 to 10 nm were thus obtained. The liquid phase hydrogenation of c,t,t-1,5,9-cyclododecatriene was carried out on these catalysts. A structure-sensitivity was observed with a decrease of TOF on smallest Pd particles. The highest yield to half-hydrogenated cyclododecene was observed on large Pd particles (∼10 nm).
Graphical abstractPd/C catalysts were prepared by ion-exchange and precipitation/deposition methods on various activated carbons with Pd particles ranging from 1.5 to 10 nm. The liquid phase hydrogenation of c,t,t-1,5,9-cyclododecatriene was carried out on these catalysts. A structure-sensitivity was observed with a decrease of TOF on smallest Pd particles. The highest yield to half-hydrogenated cyclododecene was observed on large Pd particles (∼10 nm).Figure optionsDownload full-size imageDownload as PowerPoint slide
