The influence of electrodialytic remediation on dioxin (PCDD/PCDF) levels in fly ash and air pollution control residues

•Dioxin levels in MSW fly ash and APC residues ranged between 4.85 and 197 ng g−1.•Dioxins do not dissolve from the residues during electrodialytic treatment.•Dioxin levels increase up to 2-fold due to dissolution of fly ash/APC residues.

Fly ash and Air Pollution Control (APC) residues collected from three municipal solid waste incinerators in Denmark and Greenland were treated by electrodialytic remediation at pilot scale for 8–10 h. This work presents for the first time the effect of electrodialytic treatment on polychlorinated dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF), and how these levels impact on the valorization options for fly ash and APC residue.PCDD/PCDF levels in the original residues ranged between 4.85 and 197 ng g−1, being higher for the electrostatic precipitator fly ash. The toxic equivalent (TEQ) varied ten fold, ranging 0.18–2.0 ng g−1 I-TEQ, with penta and hexa-homologs being most significant for toxicity.After the electrodialytic treatment PCDD/PCDF levels increased in the residues (between 1.4 and 2.0 times). This does not mean PCDD/PCDF were synthesized, but else that soluble materials dissolve, leaving behind the non-water soluble compounds, such as PCDD/PCDF. According to the Basel Convention, PCDD/PCDF levels in these materials is low (<15 μg WHO-TEQ kg−1) and the fly ash and APC residue could eventually be valorized, for instance as construction material, provided end-of-waste criteria are set and that a risk assessment of individual options is carried out, including the end-of-life stage when the materials become waste again.

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