Article ID Journal Published Year Pages File Type
44086 Applied Catalysis A: General 2007 9 Pages PDF
Abstract

Keggin-type supported polyoxometalates (supported-H3PW12O40 and H3PMo12O40) were found to be efficient catalysts for preparation of 1,1-diacetates under solvent-free conditions. Deprotection of the resulting 1,1-diacetates were achieved using the same catalysts in acetonitrile solvent. This new method consistently has the advantage of excellent yields and short reaction times. Further, the catalysts can be reused for several times but they will be less active.

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Physical Sciences and Engineering Chemical Engineering Catalysis
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