| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 44188 | Applied Catalysis A: General | 2006 | 6 Pages |
Abstract
Polymer-bound piperazine was readily prepared from Merrifield resin and was used as a robust support for immobilization of molybdenum hexacarbonyl. This polymer-supported molybdenum catalyst shows high activity in the epoxidation of various alkenes in the presence of tert-butylhydroperoxide (TBHP). This new heterogenized molybdenum catalyst can be recovered and reused for eight times without loss of its activity.
Graphical abstractThe catalytic activity of Mo(CO)6 supported on polystyrene in the epoxidation of alkenes with TBHP was studied in CCl4. Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Gholamhossein Grivani, Shahram Tangestaninejad, Mohammad Hossein Habibi, Valiollah Mirkhani, Majid Moghadam,