Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
44276 | Applied Catalysis A: General | 2006 | 8 Pages |
Abstract
The synthesis of a bis-silylated 15-membered azatriolefinic macrocycle is described as well as its co-gelification with tetraethyl orthosilicate. The resulting material was treated with Pd(dba)2 affording an hybrid organic–inorganic material containing macrocyclic palladium(0) complex covalently bonded to the silica matrix. The activity of this material as catalyst or precatalyst in Suzuki cross-coupling and telomerization of butadiene with methanol and phenol is presented.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Belén Blanco, Marina Brissart, Marcial Moreno-Mañas, Roser Pleixats, Ahmad Mehdi, Catherine Reyé, Sandrine Bouquillon, Françoise Hénin, Jacques Muzart,