Article ID Journal Published Year Pages File Type
4429754 Science of The Total Environment 2012 9 Pages PDF
Abstract

Enhanced sand–clay mixtures have been prepared by using a sandstone arkosic material and have been evaluated for consideration as landfill liners. A lab-scale test was carried out under controlled conditions with different amended natural sandstones whereby leachate was passed through the compacted mixtures. The compacted samples consisted of siliceous sand (quartz–feldspar sand separated from the arkose sandstone) and clay (purified clay from arkose sandstone and two commercial bentonites) materials that were mixed in different proportions. The separation of mineral materials from a common and abundant natural source, for soil protection purposes, is proposed as an economic and environmentally efficient practice. The liner qualities were compared for their mineralogical, physicochemical and major ions transport and adsorption properties. Although all samples fulfilled hydraulic conductivity requirements, the addition of bentonite to arkose sandstone was determined to be an effective strategy to decrease the permeability of the soil and to improve the pollutants retention. The clay materials from arkose sandstone also contributed to pollutant retention by a significant improvement of the cation exchange capacity of the bulk material. However, the mixtures prepared with clay materials from the arkose, exhibited a slight increase of hydraulic conductivity. This effect has to be further evaluated.

► Pollutants of methanogenic leachates are attenuated by addition of bentonite in soils. ► Quality of the studied materials has been assessed by mineralogical characterization and physico-chemical properties. ► Geochemical model establishes that these materials have a good behavior as barriers after 20 years.

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Life Sciences Environmental Science Environmental Chemistry
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