Article ID Journal Published Year Pages File Type
4430049 Science of The Total Environment 2011 9 Pages PDF
Abstract

The predicted changes in rainfall characteristics due to climate change could adversely affect stormwater quality in highly urbanised coastal areas throughout the world. This in turn will exert a significant influence on the discharge of pollutants to estuarine and marine waters. Hence, an in-depth analysis of the effects of such changes on the wash-off of volatile organic compounds (VOCs) from urban roads in the Gold Coast region in Australia was undertaken. The rainfall characteristics were simulated using a rainfall simulator. Principal Component Analysis (PCA) and Multicriteria Decision tools such as PROMETHEE and GAIA were employed to understand the VOC wash-off under climate change. It was found that low, low to moderate and high rain events due to climate change will affect the wash-off of toluene, ethylbenzene, meta-xylene, para-xylene and ortho-xylene from urban roads in Gold Coast. Total organic carbon (TOC) was identified as predominant carrier of toluene, meta-xylene and para-xylene in < 1 μm to 150 μm fractions and for ethylbenzene in 150 μm to > 300 μm fractions under such dominant rain events due to climate change. However, ortho-xylene did not show such affinity towards either TOC or TSS (total suspended solids) under the simulated climatic conditions.

Research highlights► Low, low to moderate and high rain events due to climate change will affect wash-off of the traffic generated VOCs.► TOC could be regarded as main carrier of VOCs in wash-off under changed climatic conditions in fractions 1- > 300 µm. ► Removal of toluene, meta and para-xylene from stormwater could be achieved by targeting TOC in < 1- 150 µm fractions. ► TOC in 150- > 300 µm fractions could be targeted for the removal of ethylbenzene from stormwater. ► Ortho-xylene’s wash-off is independent under changed climatic conditions.

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Life Sciences Environmental Science Environmental Chemistry
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