Article ID Journal Published Year Pages File Type
44304 Applied Catalysis A: General 2006 6 Pages PDF
Abstract

Carbon supported Pt nanoparticles were prepared in aqueous solutions by two methods: (1) room temperature NaBH4 reduction of H2PtCl6 with (Pt-1) or without (Pt-2) sodium citrate as the stabilizing agent and (2) microwave-assisted reduction of H2PtCl6 at boiling temperature using citrate as the reducing agent cum stabilizer (Pt-3 and Pt-4). The catalysts were characterized by X-ray diffraction, energy dispersive X-ray microanalysis and transmission electron microscopy, and their activities in room temperature methanol electrooxidation were evaluated by cyclic voltammetry and benchmarked against a commercial E-TEK catalyst with the same Pt loading. TEM showed smaller Pt particles if citrate was present in the synthesis, with average particle sizes of 4.0 and 2.2 nm for Pt-1 and Pt-3, respectively. While the presence of citrate was generally beneficial to forming smaller and more uniform Pt nanoparticles, a large excess of citrate (H2Cyt−:PtCl62− = 20:1) in the microwave synthesis had led to a decrease in catalytic activity. The microwave-synthesized Pt/C obtained using a smaller excess of citrate (H2Cyt−:PtCl62− = 5:1) demonstrated the best mass activity, surpassing the performance of the commercial catalyst. In addition, a size effect was found in this study: with the decrease in the platinum particle size in the range of 2.2–4 nm, the specific activity of Pt for room temperature methanol oxidation also decreased.

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
Authors
, , ,