Development and identification of an integrated waterworks model for trihalomethanes simulation

To evaluate the impact that new trihalomethanes (THMs) regulations will have on the performance of conventional waterworks in China, we developed an integrated waterworks model to simulate the dynamic behavior of THMs and other associated components, e.g. organic matter, ammonia, and residual chlorine, throughout the conventional water treatment process, which included pre-chlorination, coagulation-flocculation, sedimentation, filtration and post-chlorination. A comprehensive kinetic scheme that takes into account both the physical and biological mechanisms involved in the water treatment processes and the chemical reactions that result from chlorination was proposed for model conceptualization. In addition, the Petersen matrix was designed to present the model and formulate the mass balance equations for the model variables. The model was then identified using the Hornberger–Spear–Young (HSY) algorithm and tested against field data from the Qingzhou Waterworks in Macao, China. Despite gross uncertainty associated with the field data, the model could generally provide good predictions of the simulated variables and meet the management purposes. Furthermore, the identified model parameters agreed well with values that were reported in the literature and could be reasonably interpreted.