Occurrence of fossil organic matter in modern environments: Optical, geochemical and isotopic evidence

This study relates to the input and fate of fossil organic matter (FOM) in the modern environment, and focuses on two experimental watersheds overlying Jurassic marls: Le Laval and Le Brusquet (1 km2 in area), located near Digne, Alpes-de-Haute-Provence, France. Considering that FOM delivery is mainly a result of different processes affecting sedimentary rocks [(bio)chemical and mechanical weathering], samples from different pools were collected: bedrocks, weathering profiles, soils and riverine particles. The samples were examined using complementary techniques: optical (palynofacies methods), geochemical (Rock-Eval 6 pyrolysis, C/N ratio), molecular (gas chromatography/mass spectrometry) and isotopic (stable C isotopic composition). As a result, FOM markers were identified and tracked through the different pools. The results highlight the contribution of FOM, which can be found in all the studied pools. Transfer of FOM between bedrocks/weathering profiles (governed mainly by chemical weathering) and bedrocks/riverine particles (governed mainly by mechanical weathering) reveals any qualitative change. Weathering profiles/soils transition [governed by (bio)chemical weathering] is characterized by alteration of the FOM, which is difficult to describe because fossil material is mixed with recent organic matter (ROM). Despite this latter point, the study provides evidence for a relative resistance of FOM to weathering processes and points to its contribution to the modern geosystem and the C cycle.

► Fossil organic matter contribution is significant in some modern carbon pools (soils or riverine particles). ► Fossil organic matter fate appears to be controlled by the nature of the weathering processes. ► The physical and chemical properties of fossil organic matter lead to a variation of its sensitivity toward weathering.