Characterization of recharge processes in shallow and deeper aquifers using isotopic signatures and geochemical behavior of groundwater in an arsenic-enriched part of the Ganga Plain

Arsenic concentrations in groundwater extracted from shallow aquifers in some areas of the Ganga Plain in the states of Bihar and Uttar Pradesh, exceed 50 μg L−1 and locally reach levels in the 400 μg L−1 range. The study covered 535 km2 of active flood plain of the River Ganga, in Bihar where a two-tier aquifer system has been delineated in a multi-cyclic sequence of Quaternary sand, clay, sandy clay and silty clay all ⩽∼250 m below ground surface. The research used isotopic signatures (δ18O, δ2Η, 3H, 14C) and major chemical constituents HCO3-,SO42-,NO3-,Cl-,Ca2+,Mg2+,Na+,K+,Astotal of groundwater to understand the recharge processes and groundwater circulation in the aquifers. Values of δ18O and δ2Η combined with 3H data indicate that the recharge to the As-enriched top 40 m of the deposits is modern (<50 a), predominantly meteoric, with some evaporation during infiltration, and partly from tanks and other surface water bodies. The lower part of the upper aquifer is vulnerable to mobilization of As with increasing groundwater extraction. The low As lower aquifer (max. 5 μg L−1) is hydrologically isolated from the upper aquifer and is characterized by lower 14C concentration and lower (more negative) δ18O values. Groundwater in the lower aquifer is ∼3 ka old, occurs under semi-confined to confined conditions, with hydrostatic head at 1.10 m above the head of the upper aquifer during the pre-monsoon. The recharge areas of the lower aquifer lies in Pleistocene deposits in basin margin areas with the exposed Vindhyan System, at about 55 km south of the area.

Research highlights► Sub-regional scale aquifers delineated in arsenic-enriched belt in the Ganga Plain. Isotopic fingerprint of the groundwater, from arsenic-enriched and arsenic-safe aquifers established for the first time in the Ganga Plain. ► Recharge processes and the water provenances of vertically separated Quaternary aquifers have been established. ► Mean residence time of groundwater in the deeper aquifers has been worked out using C-14 isotope. ► Water from the deeper aquifer has been correlated with the paleoclimatic model of the Middle Ganga Plain (Mid-Ganga Basin) for 6-2 ka.