Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
44408 | Applied Catalysis A: General | 2006 | 5 Pages |
Abstract
Aldehydes undergo smooth nucleophilic addition with allyl-n-tributylstannane in the presence of sulphamic acid (5 mol%, SA) under extremely mild reaction conditions to afford the corresponding homoallylic alcohols in excellent yields with high chemoselectivity. The catalyst can be recovered by simple filtration and can be recycled in subsequent reactions. The method is simple, cost-effective and environmentally benign.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
J.S. Yadav, P. Purushothama Rao, R. Srinivasa Rao, P.S.R. Reddy, K. Nagaiah, A.R. Prasad,