Investigation of the ozone and trace gases contribution to the total optical depth in the polluted urban environment of Athens

This study focuses on the determination of optical depths caused by ozone and trace gases absorption in the Chappuis band, 500–700 nm, and the contribution to the Total Minus Rayleigh Optical Depth (TMROD). The optical depths were derived using the transmission functions implemented in the SMARTS parametric model, while the Total Optical Depths (TODs) were derived by solar extinction measurements obtained in Athens during May 1995. From the data analysis it is obvious that both the ozone and trace gases contribute significantly to TMROD in the Chappuis band. More specifically, the trace gases contributions are higher for air with high pollution levels, while ozone's contribution can be significant under clear-sky conditions. Therefore, the correction in TMROD due to ozone and trace gases optical depths is necessary for an accurate determination of the Aerosol Optical Depth (AOD) in the Chappuis band. The optical depth of ozone is generally removed during the process of the AOD retrievals, since the significance of its absorption in the Chappuis band is well understood. Nevertheless, the optical depth of the trace gases (mainly NO2) is not always taken into account in the AOD retrievals, though its contribution can be significant in urban polluted atmospheres. In this respect, the present study attempts to quantify the ozone and trace gases contributions in an urban environment and to provide some new functions that help estimate the contribution of ozone to the TMROD in the Chappuis band.