Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
4452530 | Journal of Aerosol Science | 2013 | 5 Pages |
A formula is presented for calculation the particle mean square displacement normalized by the square of its mean free path as dependent on the time related to the momentum relaxation time. The obtained equation is a result of the fractal analysis of the particle trajectory being a sequence of linear segments. At very short times the motion is ballistic whereas for long times the particle starts to behave according to Einstein's theory. The slope of a log–log plot of time dependence of mean square displacement changes from two to one. The ballistic to diffusive transition is wider than that described by the Langevin equation and spans more than three decades of time.
Graphical abstractBallistic-diffusive transition model gives an estimation of step number necessary for the validity of Einstein's equation.Figure optionsDownload full-size imageDownload high-quality image (167 K)Download as PowerPoint slideHighlights► A fractal analysis applied to the Brownian particle trajectory makes it possible to formulate a ballistic-diffusive transition model. ► At very short times the motion is ballistic whereas for long times the particle starts to behave according to Einstein's theory. ► The transition is very wide and spans more than three decades of time. ► The model has experimental confirmation for particles migrating in rarefied air.