Article ID Journal Published Year Pages File Type
4472257 Waste Management 2012 5 Pages PDF
Abstract

Recycling of waste printed circuit boards (WPCBs) is an important subject not only for the protection of environment but also for the recovery of valuable materials. A feasibility study was conducted to dissolve bromine epoxy resins of WPCBs using ionic liquid (IL) of 1-ethyl-3-methylimizadolium tetrafluoroborate [EMIM+][BF4-] (nonaqueous green solvent) for recovering copper foils and glass fibers. Experimental results indicated that the initial delamination had seen from the cross-section of the WPCBs by mean of metallographic microscope and digital camera when WPCBs were heated in [EMIM+][BF4-] at 240 °C for a duration of 30 min. When temperature was increased to 260 °C for a duration of 10 min, the bromine epoxy resins of WPCBs were throughout dissolved into [EMIM+][BF4-] and the separations of copper foils and glass fibers from WPCBs were completed. This clean and non-polluting technology offers a new way to recycle valuable materials from WPCBs and prevent the environmental pollution of WPCBs effectively.

► Recycling waste printed circuit boards (WPCBs) by ionic liquid (IL). ► The epoxy resins of WPCBs are slightly dissolved to produce initial delamination at 240 °C. ► The epoxy resins of WPCBs are removed by [EMIM+][BF4-] at 260 °C.

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Physical Sciences and Engineering Earth and Planetary Sciences Geotechnical Engineering and Engineering Geology
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