| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 4480853 | Water Research | 2016 | 9 Pages |
•Chlorination of phenylalanine produces phenylacetonitrile as major N-DBP.•Phenylacetonitrile is stable in chlorinated drinking water with half-life > 30 days.•Phenylacetonitrile is detected at μg/L in drinking water samples from two continents.•Odor of phenylacetonitrile has various descriptors and a threshold <1 μg/L.
Unregulated disinfection byproducts (DBPs), including nitrogenous disinfection byproducts (N-DBPs), originating from chlorination of the precursor amino acid phenylalanine in aqueous systems, were identified in laboratory reactions and distributed tap. The major N-DBP identified was phenylacetonitrile, and minor DBPs of benzyl chloride, phenylacetaldehyde, 2-chlorobenzyl cyanide, and 2, 6-diphenylpyridine were also formed. Phenylacetonitrile was generated through decarboxylation, dechlorination and/or hydrolysis processes. With an aromatic structure, phenylacetonitrile has an unpleasant odor of various descriptors and an odor threshold concentration of 0.2 ppt-v as measured through gas chromatography-olfactometry. The half-life of phenylacetonitrile in reagent water and chlorinated water at 19 °C were 121 h and 792 h, respectively. The occurrence of phenylacetonitrile as an N-DBP in tap water was investigated for the first time; the results revealed that μg/L concentrations were present in nine different distributed drinking waters in China and the United States. Phenylacetonitrile deteriorates the aesthetic quality of drinking water and may present risk due to its prolonged existence in drinking water, especially in the presence of residual chlorine.
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