Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
4480900 | Water Research | 2016 | 10 Pages |
•Mesoporous and ferromagnetic Fe/Al bimetallic particles were synthesized.•The properties, compositions, and structures of Fe/Al bimetals were studied.•Fe/Al bimetals exhibited good As(III) removal capability and stability.•Adsorption, oxidation, and reduction behavior and mechanism of arsenic were investigated.
In this study, mesoporous iron/aluminum (Fe/Al) bimetallic particles were synthesized and employed for the removal of aqueous As(III). Scanning electron microscopy and energy dispersive spectroscopy (SEM-EDS), Brunauer-Emmett-Teller (BET) analysis method, Vibrating-sample magnetometry (VSM), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectroscopy (FTIR) were employed to characterize the Fe/Al bimetals before and after reaction with As(III). The physical properties, compositions, and structures of Fe/Al bimetallic particles as well as the As(III) removal mechanism were investigated. The characterization of the bimetallic particles after the reaction has revealed the removal of As(III) is a complex process including surface adsorption and oxidation, and intraparticle reduction. The good As(III) removal capability and stability of the Fe/Al bimetallic particles exhibited its great potential as an effective and environmental friendly agent for As(III) removal from water.
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