Article ID Journal Published Year Pages File Type
4481378 Water Research 2014 11 Pages PDF
Abstract

•Treatability of hypersaline brine contaminated with benzoic acid was investigated.•Bacterial cultures obtained are suitable for treatment of hypersaline wastewater.•Long-term DOC removal of nearly 98% in continuous flow reactor.•Continuous reactor showed higher process stability than batch or fed-batch systems.•Instant elimination of about 85% of benzoic acid via chemical precipitation.

Eight mixed cultures able to degrade benzoic acid under saline conditions were established and kinetic parameters were determined in batch processes with cultures SBM002 (0.5 g d−1·g oDM−1), SBM003 (0.7 g d−1·g oDM−1) and SBM007 (2.2 g d−1·g oDM−1) showing the highest degradation rates. Treatability of an industrial waste water (12 g L−1 benzoic acid, 82 g L−1 NaCl) by these cultures was proven in a fed-batch system (SBM002 & SBM003) and a continuous flow reactor (SBM007). The performance of the continuous flow reactor was 15-times higher compared to the fed-batch system due to the change of inocula, higher concentration of ammonia as nutrient and less accumulation of possibly toxic catecholic compounds. Average DOC reduction was found to be 98% at 100 g L−1 NaCl and 1.2 g L−1 benzoic acid under these conditions. Pre-treatment of the waste water via chemical precipitation by acidification to pH 3.5 diminished the concentration of benzoic acid to 2.1 g L−1. In a combined chemical-biological process the volume of the bioreactor is reduced to 15% compared to a pure biological process. A comparison of operational costs for these three alternatives is presented.

Related Topics
Physical Sciences and Engineering Earth and Planetary Sciences Earth-Surface Processes
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