| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 4481693 | Water Research | 2014 | 11 Pages |
•Lab assessment of sources and environmental factors affecting FOG deposit properties.•Properties of calcium fatty acid salts depend on pH and temperature within sewer system.•Fatty acid profile of calcium fatty acid salts are identical to the source fat profile.•Fate of fatty acids in sewers is suggested leading to accumulation of palmitic.
Understanding the formation of Fat, Oil, and Grease (FOG) deposits in sewer systems is critical to the sustainability of sewer collection systems since they have been implicated in causing sewerage blockages that leads to sanitary sewer overflows (SSOs). Recently, FOG deposits in sewer systems displayed strong similarities with calcium-based fatty acid salts as a result of a saponification reaction. The objective of this study was to quantify the factors that may affect the formation of FOG deposits and their chemical and rheological properties. These factors included the types of fats used in FSEs, environmental conditions (i.e. pH and temperature), and the source of calcium in sewer systems. The results of this study showed that calcium content in the calcium based salts seemed to depend on the solubility limit of the calcium source and influenced by pH and temperature conditions. The fatty acid profile of the calcium-based fatty acid salts produced under alkali driven hydrolysis were identical to the profile of the fat source and did not match the profile of field FOG deposits, which displayed a high fraction of palmitic, a long chain saturated fatty acid. It is hypothesized that selective microbial metabolism of fats and/or biologically induced hydrogenation may contribute to the FOG deposit makeup in sewer system. Therefore, selective removal of palmitic in pretreatment processes may be necessary prior to the discharge of FSE wastes into the sewer collection system.
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