Article ID Journal Published Year Pages File Type
4484355 Water Research 2009 13 Pages PDF
Abstract

Rapid small-scale column tests (RSSCTs) examined the removal of 29 endocrine disrupting compounds (EDCs) and pharmaceutical/personal care products (PPCPs). The RSSCTs employed three lignite variants: HYDRODARCO 4000 (HD4000), steam-modified HD4000, and methane/steam-modified HD4000. RSSCTs used native Lake Mead, NV water spiked with 100–200 ppt each of 29 EDCs/PPCPs. For the steam and methane/steam variants, breakthrough occurred at 14,000–92,000 bed volumes (BV); and this was 3–4 times more bed volumes than for HD4000. Most EDC/PPCP bed life data were describable by a normalized quantitative structure–activity relationship (i.e. QSAR-like model) of the form: BVp=((TPV×ρmc)(ⅇ0.2812×pHs)CV×Co)(0.2758×χ8p+0.0011×FOSA)where TPV is the pore volume, ρmc is the apparent density, CV is the molecular volume, Co is the concentration, 8χp depicts the molecule's compactness, and FOSA is the molecule's hydrophobic surface area.

Related Topics
Physical Sciences and Engineering Earth and Planetary Sciences Earth-Surface Processes
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