Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
4485441 | Water Research | 2007 | 14 Pages |
Abstract
This study investigated the effect of the COD/SO42â ratio (4 and 1) and the sulfide concentration on the performance of thermophilic (55 °C) acidifying (pH 6) upflow anaerobic sludge bed reactors fed with sucrose at an organic loading rate of 4.5 g COD lreactorâ1 dayâ1. Sulfate reduction efficiencies amounted to 65% and 25-35% for the COD/SO42â ratios of 4 and 1, respectively. Acidification was complete at all the tested conditions and the electron flow was similar at the two COD/SO42â ratios applied. The stepwise decrease of the sulfide concentrations in the reactors with a COD/SO42â ratio of 1 by N2 stripping caused an immediate stepwise increase in the sulfate reduction efficiencies, indicating a reversible inhibition by sulfide. The degree of reversibility was, however, affected by the growth conditions of the sludge. Acidifying sludge pre-grown at pH 6, at a COD/SO42â ratio of 9 and exposed for 150 days to 115 mg lâ1 sulfide, showed a slower recovery from the sulfide inhibition than a freshly harvested sludge from a full scale treatment plant (pH 7 and COD/SO42â=9.5) exposed for a 70 days to 200 mg lâ1 sulfide. In the latter case, the decrease of the sulfide concentration from 200 to 45 mg lâ1 (35 mg lâ1 undissociated sulfide) by N2 stripping caused an immediate increase of the sulfate reduction efficiency from 35% to 96%.
Related Topics
Physical Sciences and Engineering
Earth and Planetary Sciences
Earth-Surface Processes
Authors
S.I.C. Lopes, X. Wang, M.I. Capela, P.N.L. Lens,