Reduction of nitrobenzene in groundwater by iron nanoparticles immobilized in PEG/nylon membrane

The highly reactive iron nanoparticles (NPs) immobilized in nylon membrane were synthesized and characterized, and the reduction of nitrobenzene (NB) in groundwater by the NPs was investigated. Environmental scanning electron microscopy (ESEM) images showed that the NPs distributed homogeneously on the membrane surface without agglomeration. X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analyses revealed that the NPs immobilized in membrane were mainly composed of Fe-oxides rather than zero-valent iron. Thermogravimetric (TG) analysis suggested that the weight percentage of the immobilized NPs and the oxygen introduced to the reacted sample after 80 min reaction were about 18.5% and 13%, respectively. Moreover, Fourier transform infrared (FTIR) analysis further demonstrated the changes on the membrane surface after thermal grafting, NPs immobilizing and reacting for 80 min. Using the reactive NPs immobilized in nylon membrane, NB in groundwater was rapidly and quantitatively decreased by 68.9% just in the first 20 min, the Fe2+ associated with the iron NPs immobilized in PEG/nylon66 membrane was mainly responsible for this reduction. The reaction appeared to follow pseudo-first-order kinetics and the rate constants increased upon decreasing the pH value. The samples we prepared exhibited good corrosion resistance for humic acid (HA) but had a short-term performance for NB degradation. More so, the groundwater chemistry had a negative influence on the reactivity of membrane immobilized NPs.

Research Highlights► The NPs immobilized in nylon membrane efficiently degraded the NB in groundwater. ► The immobilized NPs were mainly composed of Fe-oxides rather than Fe0. ► Ground water conditions significantly influenced the behavior of immobilized NPs.