Sources and distribution of aliphatic and polyaromatic hydrocarbons in coastal sediments from the Ushuaia Bay (Tierra del Fuego, Patagonia, Argentina)

The environmental quality of Ushuaia Bay, located at the southernmost tip of South America, is affected by the anthropogenic pressure of Ushuaia city. In this study, levels and sources of hydrocarbons in coastal sediments were assessed. Aliphatic hydrocarbon fractions ranged between 5.5 and 1185.3 μg/g dry weight and PAHs from not detected to 360 ng/g. Aliphatic diagnostic indices, the nalkanes homologous series occurrence, Aliphatic Unresolved Complex Mixtures (AliUCMs), and pristane and phytane isoprenoids indicated a petrogenic input. Some sites showed biogenic features masked by the anthropogenic signature. Particularly in port areas biodegradation processes were evident. PAH ratios showed a mixture of petrogenic and pyrogenic sources. Aliphatic and aromatic UCMs were strongly correlated, reflecting chronic pollution. Three areas were distinguished inside the bay: (1) east, with low hydrocarbons impact; (2) central, where hydrocarbons accumulation was related to source proximity and sediment characteristics; (3) south-west, where sediment characteristics and current circulation favour hydrocarbons accumulation.

► We assessed aliphatic and aromatic hydrocarbon levels and probable sources in coastal sediments of Ushuaia Bay, Argentina. ► Aliphatic diagnostic indices indicated a petrogenic signature with minor terrestrial biogenic input in some stations. ► Biodegradation processes were evident, particularly in port areas. ► PAH ratios showed a mixture of both petrogenic and pyrogenic hydrocarbon sources. ► Hydrocarbon pollution was associated with ports, sediment characteristics, and current circulation inside the Bay.