Article ID Journal Published Year Pages File Type
45761 Applied Catalysis B: Environmental 2013 6 Pages PDF
Abstract

A novel method for intercalating silver salt into bentonite interlayers is described. The very fine Ag3PO4 crystalline grains (less than 0.45 nm) were obtained in the interlayers of bentonite (Ag3PO4-Ben). Ag3PO4-Ben was characterized by XRD, FTIR, XRF, XPS and UV–vis diffuse reflectance spectroscopy. Ag3PO4-Ben particles exhibited high catalytic efficiency for Orange II degradation under visible light irradiation. The photocatalytic activity is attributed to the small-sized Ag3PO4 crystal immobilized in bentonite and the strong adsorption of dye on bentonite. The special structure of bentonite and the microenvironment around the catalysis enhanced the stability.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Fine Ag3PO4 crystalline grains (smaller than 0.45 nm) were immobilized in bentonite. ► Ag3PO4 photocatalytic activity and stability were improved. ► The content of silver in the photocatalyst decreased from 77.3 wt% to 10.7 wt%.

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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