Studying the sensitivity of pollutants’ concentrations caused by variations of chemical rates

A systematic procedure for sensitivity analysis of a case study in the area of air pollution modeling has been performed. Contemporary mathematical models should include a large set of chemical and photochemical reactions to be established as a reliable simulation tool. The Unified Danish Eulerian Model is in the focus of our investigation as one of the most advanced large-scale mathematical models that describes adequately all physical and chemical processes.Variance-based methods are one of the most often used approaches for providing sensitivity analysis. To measure the extent of influence of the variation of the chemical rate constants in the mathematical model over pollutants’ concentrations the Sobol’ global sensitivity indices are estimated using efficient techniques for small sensitivity indices to avoid a loss of accuracy. Studying relationships between input parameters and the model’s output as well as internal mechanisms is very useful for a verification and an improvement of the model and also for development of monitoring and control strategies of harmful emissions, for a reliable prediction of the final output of scenarios when the concentration levels of pollutants are exceeded. The proposed procedure can also be applied when other large-scale mathematical models are used.