The thermodynamic limit of quantum Coulomb systems Part I. General theory

This article is the first in a series dealing with the thermodynamic properties of quantum Coulomb systems.In this first part, we consider a general real-valued function E defined on all bounded open sets of R3. Our aim is to give sufficient conditions such that E has a thermodynamic limit. This means that the limit E(Ωn)|Ωn|−1 exists for all ‘regular enough’ sequence Ωn with growing volume, |Ωn|→∞, and is independent of the considered sequence.The sufficient conditions presented in our work all have a clear physical interpretation. In the next paper, we show that the free energies of many different quantum Coulomb systems satisfy these assumptions, hence have a thermodynamic limit.