Article ID Journal Published Year Pages File Type
4699999 Chemical Geology 2010 8 Pages PDF
Abstract

Compilations of experimental data allow the clinopyroxene Fe = Mg exchange equilibrium constant (Kd = (XFe/XMg)Clinopyroxene / (XFe/XMg)Melt) to be parameterized. Values of Kd increase with increasing pressure, temperature, Log fO2, melt CaO, NBO/TO, LnMgO, MgO#; and with decreasing melt SiO2, and Na2O + K2O. Multiple regression analysis yields improved fits, including some based solely on mineral compositional data. These parameterizations allow improved petrogenetic hypothesis testing for clinopyroxene-bearing assemblages.

Related Topics
Physical Sciences and Engineering Earth and Planetary Sciences Geochemistry and Petrology
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