Comparing the activity of aluminum in two B horizons developed from volcanic ash deposits in Japan, dominated by short-range ordered aluminosilicates and crystalline clay minerals, respectively

Mechanisms controlling the activity of free aluminum (Al) in Bw1 horizons of soils developed from volcanic ash deposits in Japan were investigated by means of acid–base titrations and kinetic studies. In a Bw1 horizon, with a high content of acid-oxalate extractable Al, soil solution reached equilibrium with short-range ordered aluminosilicates in the order of days. Relatively fast kinetics of the release and precipitation of Al and Si indicate a high reactivity of short-range ordered aluminosilicates in the soil. In the Bw1 horizon of an adjacent soil, with a high content of crystalline clay minerals like halloysite and interlayered vermiculite, solution remained well undersaturated with respect to short-range ordered aluminosilicates and aluminum hydroxide. Apparent equilibrium with respect to halloysite occurred after more than 30 days. This halloysite (logKso0=3.74±0.02 (25 °C)) has a solubility that is less than that reported in the literature (logKso0=4.36 (25°C)). Our findings suggest that different reactive aluminosilicates may control the activity of free Al in sub-surface horizons of volcanic ash soils with different mineralogy.