Composition, pre-eruptive zonation, and geochronologic significance of the ∼450 ka Diamante Tuff, Andean Cordillera (34°S), Argentina

Vertical geochemical sampling through the Diamante Tuff establishes patterns of zonation in the pre-eruption magma. Volcanic glass demonstrates a roofward increase in Fe and Cl, and a roofward decrease in Ca. Trace elements have no measurable zonation. Welded volcanic glass shows post-eruption loss of Fe, Mg and Cl as well as K gain. Our reported glass chemistry provides robust criteria for correlation to other localities. The Diamante Tuff is an important stratigraphic marker and recognition of this unit provides age control on Quaternary deposits, allowing determination of process rates and elucidating timing of tectonic and geomorphic activity.