Article ID Journal Published Year Pages File Type
4764252 Chinese Journal of Chemical Engineering 2016 30 Pages PDF
Abstract
The molar heat capacities (Cp) of guaiacol (CAS 90-50-1) and acetyl guaiacol ester (AGE, CAS 613-70-7) were determinated from 290 K to 350 K by differential scanning calorimetry (DSC), and expressed as a function of temperature. Two kinds of group contribution models were used to estimate the molar heat capacities of both guaiacol and AGE, the average relative deviation is less than 10%. The standard molar enthalpies of combustion of guaiacol and AGE were − 3590.0 kJ·mol− 1 and − 4522.1 kJ·mol− 1 by a precise thermal isolation Oxygen Bomb Calorimeter. The standard molar enthalpies of formation of guaiacol and AGE in a liquid state at 298.15 K were calculated to be − 307.95 kJ·mol− 1 and − 448.72 kJ·mol− 1, respectively, based on the standard molar enthalpies of combustion. The thermodynamic properties are useful for exploiting the new synthesis method, engineering design and industry production of AGE using guaiacol as a raw material.
Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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