Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
4766363 | Dyes and Pigments | 2017 | 7 Pages |
Abstract
We have synthesized three pairs of enantiomers for chiral bisporphyrins H1-H3 by connecting two zinc(II) porphyrin units to a homochiral (R)-(+)- or (S)-(â)-1,1â²-bi-2-naphthol moiety with ester or ether linkages. The intramolecular chirality induction and intermolecular chirality modulation events have been studied by UV-Vis, 1H NMR and CD spectroscopic techniques with the assistance of DFT molecular modeling.221
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Wenxin Lu, Likun Li, Huifang Yang, Luyang Zhao, Dongdong Qi, Yongzhong Bian, Jianzhuang Jiang,