Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
4766784 | Electrochimica Acta | 2017 | 39 Pages |
Abstract
This paper reports the electrocatalytic properties of layer by layer (LbL) films formed by gold nanoparticles stabilized in propylpyridinium silsesquioxane polymer (AuNPs-SiPy+) as polycation, and prussian blue nanoparticles (PB) as polyanion with synergistic effect in the H2O2 reduction. Under optimized synthesis conditions by factorial design, the TEM images of gold nanoparticles showed spherical shape with diameter ranging from 2 to 35Â nm. All modified electrodes with inorganic materials were explored by spectroscopy (UV-Vis and FTIR) and electrochemical techniques (Cyclic Voltammetry, Chronoamperometry and Electrochemical Impedance Spectroscopy). We demonstrated that the presence of gold nanoparticles greatly enhanced the electroactive properties of the multilayer films providing interesting electrochemical features and excellent sensitivity in the electrocatalytic reduction of hydrogen peroxide, compared to electrode containing only the silsesquioxane polymer as cationic polyelectrolyte.
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Authors
Giselle Nathaly Calaça, Cristiane Andreia Erdmann, Ana LetÃcia Soares, Christiana Andrade Pessôa, Sergio Toshio Fujiwara, Jarem Raul Garcia, Marcio Vidotti, Karen Wohnrath,