Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
4766895 | Electrochimica Acta | 2017 | 27 Pages |
Abstract
A novel, facile and scalable process of simultaneous activation and templating is developed for in situ synthesis of graphene-enhanced 3D hierarchical porous carbon nanobelt networks uniformly anchored with polycrystalline Fe3O4 nanoparticles (5-45Â nm) (Fe3O4-rGO/poly(vinyl alcohol) (PVA)-derived carbon) as a high-performance supercapacitor electrode. During the synthesis, 3D self-assembled NaCl particles are adopted as a structural template to direct the growth of 3D carbon nanobelt networks with interconnected macropores, KOH is used as an activating reagent to generate porous nanobelts with masses of micro-, meso- and macropores, and graphene sheets behave as a chemical activator to promote the growth of hierarchical porous thin nanobelts. The resulting Fe3O4-rGO/PVA-derived carbon electrode leads to a combination of the redox pseudo-capacitance of Fe3O4 and the electric double-layer capacitance of the carbon species with a remarkably high capacitivity (538.8Â FÂ gâ1 at 5Â AÂ gâ1) and outstanding cycle performance (â¼590Â FÂ gâ1 after 5000 cycles at 5Â AÂ gâ1). This work offers a new strategy for preparation of 3D hierarchical porous carbon networks for future applications.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Xing Yu, Mengyi Wang, Annie Gagnoud, Yves Fautrelle, Rene Moreau, Xi Li,