Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
4768252 | Fuel | 2018 | 7 Pages |
Abstract
Fine particles are significantly harmful to the human body and the atmospheric environment. However, the electrostatic precipitator (ESP) removal efficiency for PM2.5 is low, therefore chemical agglomeration technology, which uses various chemical agents to induce particle agglomeration, improving the efficiency of ESP seems to be a promising pretreatment technology. In the present contribution a combination of experimental and DFT calculations has been used to study this technique. We used water, pectin and sodium alginate solutions as agglomeration agents. Experimental results showed that sodium alginate solutions is most effective, the particle diameter increased from 0.1â¯Î¼m to 1â¯Î¼m and the ESP removal efficiency of number concentration increased above 20% with chemical agglomeration technology. In theoretical studies we simulated various molecular clusters consisting of water, pectin and sodium alginate in combination with simple model silica particles (TOS) by using DFT calculations to explore the internal interactions in ESP system at molecular level. In our results, water, pectin and sodium alginate interacted with TOS by hydrogen bond, with interaction energy of 4.0â¯kcal/mol, 6.7â¯kcal/mol and 7.4â¯kcal/mol, respectively. Finally, according to the experimental and theoretical results, the chemical agglomeration models were put forward.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Hu Bin, Yi Yang, Zhou Lei, Shen Ao, Liang Cai, Yang Linjun, Szczepan Roszak,