Article ID Journal Published Year Pages File Type
4769271 Hydrometallurgy 2017 28 Pages PDF
Abstract
The extraction of both Ga(III) and Ge(IV) was achieved using an organic system consisting of tri(octyl-decyl) amine (N235), tributyl phosphate (TBP) in sulfonated kerosene from iron-removed leach solution. The extraction equilibria of both metals were obtained within 10 min at 30 °C. More than 99.0% Ga(III) and 99.8% Ge(IV) were extracted in a three-stage counter current extraction using an organic system consisting of 20% (v/v) N235, 10% (v/v) TBP and 70% (v/v) sulfonated kerosene at an A/O ratio of 3:1 and 30 °C for 10 min. Over 99.0% Ga(III) was selectively stripped from the loaded organic solution by three-stage counter current stripping using 2.5 mol/L H2SO4 at an A/O ratio of 1:2 and 30 °C for 15 min, resulting in a loaded strip liquor containing 3.8 g/L Ga(III). After Ga(III) stripping, 99.8% Ge(IV) was stripped by two-stage counter current stripping using 4 mol/L NaOH at an A/O ratio of 1:3 and 40 °C for 15 min, resulting in a final loaded strip liquor containing 8.3 g/L Ge(IV). A conceptual flowsheet has been developed to recover Ga(III) and Ge(IV) from zinc refinery residues using two-stage leaching with H2SO4 and oxalic acid, subsequently, iron removal with iron powder and solvent extraction with N235 and TBP.
Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
Authors
, , , , , , ,