Article ID Journal Published Year Pages File Type
48558 Applied Catalysis B: Environmental 2007 5 Pages PDF
Abstract

The formation of organo-nitrite and -nitro species (R-ONO and R-NO2) as intermediates during the selective catalytic reduction (SCR) of NOx by C3H6 over Ag/Al2O3 was investigated by temperature-programmed desorption (TPD) and in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). The addition of KBr to Ag/Al2O3 catalyses the isomerization of R-NO2 to R-ONO on KBr-Ag/Al2O3, which confirms the presence of R-NO2 on Ag/Al2O3.

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Physical Sciences and Engineering Chemical Engineering Catalysis
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