Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
48907 | Applied Catalysis B: Environmental | 2007 | 6 Pages |
Abstract
A simplified oxidative desulfurizataion (ODS) catalytic system composed of Na2WO4, 30% H2O2 and CH3CO2H has been found suitable for the deep removal of sulfur in diesel. By combining ODS and methanol extraction, the sulfur level in a commercial diesel has been reduced from 1100 ppm to 40 ppm. Treatment of model solutions of octane containing dibenzothiophene and 4,6-dimethyl dibenzothiophene with our ODS system shows 100% conversion of the thiophenes to sulfones at 70 °C in less than 1 h.
Related Topics
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Authors
Farhan Al-Shahrani, Tiancun Xiao, Simon A. Llewellyn, Sami Barri, Zheng Jiang, Huahong Shi, Gary Martinie, Malcolm L.H. Green,