Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
4907556 | Journal of Electroanalytical Chemistry | 2017 | 6 Pages |
Abstract
A lipophilic and electron-rich metallophthalocyanine Mn(III)Cl(α,αâ²-n-OC5H11)8Pc has been synthesized and characterized. A series of electrochemical experiments demonstrate that the Mn(III)Cl(α,αâ²-n-OC5H11)8Pc complex can be used as a catalyst for highly efficient carbon-chloride bond cleavage of environmental toxic hexachlorocyclohexanes (HCHs) through electrochemical catalysis, and that the increased catalytic efficiency is related to the enantiomeric carbon-chloride Ï-bond of HCHs.
Related Topics
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Authors
Junxia Wen, Baoqiu Yu, Tingting Huang, John Mack, Martijn Wildervanck, Tebello Nyokong, Minzhi Li, Weihua Zhu, Xu Liang,