Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
4908137 | Journal of Electroanalytical Chemistry | 2016 | 5 Pages |
â¢Immobilization of tetrazine by formation inclusion complexes with β-cyclodextrinâ¢Immobilized tetrazines keep their electrochemical and emission properties.â¢New supramolecular fluorescent poly(pyrrole β-cyclodextrin) - tetrazine filmsâ¢Fast and easy binding of different tetrazine derivatives on electrode surfacesâ¢A tetrazine-naphthalimide derivative used as a bridge between polymer and enzyme
Tetrazines were immobilized onto electrogenerated films of polypyrrole functionalized with β-cyclodextrin. Their immobilization was ascribed to the formation of the inclusion complexes between the tetrazines derivatives and the β-cyclodextrin cavity. We proved that the resulting supramolecular material kept the electrochemical and fluorescent properties of tetrazines. This original architecture was used with success as a “bridge” to immobilize the β-cyclodextrin-tagged glucose oxidase, chosen as an enzyme model, to prove the efficiency of the method to build new supra-biomolecular architectures.