Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
4908736 | Journal of Environmental Chemical Engineering | 2017 | 48 Pages |
Abstract
The preparation of porous materials using biodegradable materials has attracted much attention in the field of environmental pollution control. A non-toxic, user-friendly and inexpensive adsorbent bead was prepared from poly (lactic acid) (PLA) and activated carbon (AC) using a phase inversion technique. The porous structure of the PLA/AC bead was characterized by scanning electron microscopy and nitrogen adsorptionâdesorption methods The removal of the carcinogenic dye Rhodamine B was studied by batch equilibration method and it was found that the monolayer maximum adsorption capacity was 149.57 mg gâ1 at 60 °C, pH 4. A study of kinetics adsorption revealed that the Rhodamine B molecules diffused very rapidly into the interconnected pores of the PLA/AC 5% wt. beads and agreed very well with the intraparticle diffusion model. The negative value of Gibb's free energy indicated a spontaneous adsorption process, and the enthalpy change (23.92 kJ molâ1) implied an endothermic adsorption process. Desorption studies showed that the percentage of desorbed Rhodamine B solution increased with a decrease in pH. The results indicated that the PLA/AC bead will provide a new alternative granular adsorbent for the removal of pollutant cationic dyes from water.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Memoon Sattar, Fareeda Hayeeye, Watchanida Chinpa, Orawan Sirichote,