Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
4909670 | The Journal of Supercritical Fluids | 2017 | 7 Pages |
â¢Solubilities of five flavonoids measured, (313-333) K.â¢Flavanone, tangeritin, nobiletin, 6-hydroxyflavanone and 7-hydroxyflavone.â¢Assessment with Mendez-Santiago-Teja (MST) consistency test.â¢Correlation with entropy-based solubility parameter (eSP) model.â¢Generalized form of the MST equation for flavonoids.
Solubilities of five flavonoids (flavanone, tangeritin, nobiletin, 6-hydroxyflavanone and 7-hydroxyflavone) were measured in supercritical CO2 at (313.2-333.2) K and at pressures up to 22Â MPa. Among the solubility values of the flavonoids at 313Â K, that of flavanone was the highest (â¼10â3Â mol/mol) next to that of tangeritin and nobiletin which had almost the same range of solubility values (10â6-10â5), followed by 6-hydroxyflavanone (â¼10â7) and 7-hydroxyflavone (â¼10â8). Data had a maximum average relative deviation (ARD) of 1.69% from the Mendez-Santiago-Teja (MST) consistency test. The solubility of each flavonoid was correlated with the Peng-Robinson, entropy-based solubility parameter and a generalized form of the MST equation to within 3% ARD.
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