Electrokinetic nanoparticle injection for remediating leaks in oil well cement

The paper proposes to use a non-destructive remediation technique for the cement repair based on the electrokinetic injection of nanoparticles into the pore and crack space in the material. It shows the efficiency of the technique and presents results from injections with a variety of differently sized nanosilica, microsilica and nanoalumina particles. Characterization of the treated samples was based on microscopy observations, electrical measurements, the change in their open porosity and nanopore surface area assessed by the BET technique. It was found that the electrokinetic process and driving of particles in samples is very efficient and reduces the sample porosity by about 4-7% with respect to the initial porosity of intact specimens and 5-8% on aged samples. The BET analysis confirmed reduction of the inner pore surface area in the treated samples. Increasing level of agglomeration of particles on the surface as well as in the inner pores was observed during electrokinetic treatment and documented with the electric current measurements.