| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 49279 | Catalysis Communications | 2016 | 4 Pages |
Abstract
•Calcium catalyzed addition of ketone-derived silyl enol ethers to N-phenyl nitrones•Use of commercially available calcium(II) complex.•Calcium(II) is a relatively cheap, abundant, benign metal.•Synthesis of β-(silyloxy)amino carbonyl compounds
A method for synthesizing β-(silyloxy)amino carbonyls through the addition of ketone-derived silyl enol ethers to N-phenyl nitrones has been developed. The transformation is catalyzed by a commercially available calcium(II) complex affording β-(silyloxy)amino carbonyls in good to excellent yield.
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Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Elizabeth A. Congdon, Kristine A. Nolin,