Article ID Journal Published Year Pages File Type
49492 Catalysis Communications 2014 5 Pages PDF
Abstract

•K6As2W18 − xMoxO62 (x = 0–3) Wells–Dawson heteropolyacids were prepared.•Reduction potentials were measured by an electrochemical method.•Absorption edge energies were determined by UV–visible spectroscopy.•Vapor-phase oxidative dehydrogenation of benzyl alcohol was conducted.•Yield for benzaldehyde increased with increasing redox properties.

Redox behaviors of molybdenum-substituted Wells–Dawson tungstoarsenate heteropolyacid catalysts (α-K6As2W18 − xMoxO62 (x = 0–3)) were probed by electrochemical and UV-visible spectroscopy measurements. Reduction potential of K6As2W18 − xMoxO62 (x = 0–3) catalysts shifted to more positive potential with increasing molybdenum content. UV–visible spectroscopy analysis was conducted as a simple diagnostic method for reduction potential. Absorption edge energy determined by UV–visible spectroscopy decreased with increasing reduction potential. Gas-phase oxidative dehydrogenation of benzyl alcohol was carried out as a model reaction. Yield for benzaldehyde increased with increasing electrochemical reduction potential and with decreasing UV–visible absorption edge energy of the catalysts.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
Authors
, , , , ,