Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
49812 | Catalysis Communications | 2016 | 4 Pages |
Abstract
•Influence of TiO2 structure on CuO/TiO2 catalysts.•These are a lot of Cu+ ions and oxygen vacancies that exist on CuO/TiO2 (rutile) catalyst.•CuO/TiO2 (rutile) catalyst is readily reduced.•CO species can adsorb to form Cu+ (CO)2 and O2 can adsorb to form O2−.
The present work tentatively investigated anatase- or rutile-supported copper oxide catalysts. 5% copper oxide can be well dispersed on anatase or rutile surfaces. The copper oxide dispersed on rutile surface exists in Cu2+ and Cu+ ions, which is more readily reduced, and show higher catalytic activity of CO oxidation. The mechanism of CO oxidation over rutile support is different from anatase support.
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Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Yanxia Tang, Lihui Dong, Changshun Deng, Meina Huang, Bin Li, Hongliang Zhang,