| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 49839 | Catalysis Communications | 2012 | 5 Pages |
Abstract
Two new water-soluble diphosphacyclooctanes been synthesized and characterized by NMR and surface tension measurements. Both phosphanes proved to coordinate rhodium in a very selective way as well-defined bidentates were obtained. When used in Rh-catalyzed hydroformylation of terminal alkenes, both ligands positively impacted the reaction chemoselectivity.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Two new water-soluble diphosphadiazacyclooctanes derivatives have been synthesized. ► Phosphanes displayed a κ2-P,P coordination mode on rhodium complexes. ► High chemoselectivity was measured in terminal alkenes Rh-catalyzed hydroformylation.
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Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Jérôme Boulanger, Hervé Bricout, Sébastien Tilloy, Aziz Fihri, Christophe Len, Frédéric Hapiot, Eric Monflier,