Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
4989231 | Journal of Membrane Science | 2017 | 9 Pages |
Abstract
The application of grafted membranes based on modified poly(ethylene-alt-tetrafluoroethylene) (ETFE) in redox flow-batteries is reported. In analogy to commercial NafionĀ® 117 based membranes ETFE backbone material provides chemical, thermal, and mechanical stability. Side chains composed of 2-hydroxyethyl methacrylate (HEMA) and glycidyl methacrylate (GMA) grafted to ETFE were sulfonated to achieve the required proton exchange capacity. Application in a vanadium based redox flow-battery demonstrates the applicability of this kind of membranes for energy storage systems. The degree of grafting was identified as the key parameter to tune the membrane properties.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Filtration and Separation
Authors
Xin Li, Antonio R. dos Santos, Marco Drache, Xi Ke, Uwe Gohs, Thomas Turek, Maik Becker, Ulrich Kunz, Sabine Beuermann,